3Blue1Brown Calculus Video: Why are the unraveled rings trapezoids?
I was thinking that in real life, the unraveled ring actually is a rectangle
Think of it like a racetrack. The outer track is always slightly longer than the inner track so when you flatten it out, you approximately have quadrilateral with one edge longer than the opposite one; i.e. like a trapezoid.
So, in real life, are the unraveled rings actually rectangles or not?
Not perfectly but they become more rectangular when we take thinner rings. So an "infinitely thin ring" would be perfectly rectangular but that's a bit murky to define. When we unravel the rings of the circle, we get trapezoids.* But the thinner your rings are, the more the trapezoids look like rectangles.
This is a ring of width $1$ from a circle
Compared with a ring of width $\frac1{10}$
When we make the ring width as thin as $\frac1{100}$, it's pretty much just a very thin rectangle.
The essence of integration is that the thinner you make your rings or strips, the less the curve of the edge matters and the more they look like thin rectangles.
* We can show that the shape of the rings is trapezoidal since each they are the set of all infinitesimally thin circumferences, $2\pi r$; which are linear with respect to the radii $r$. Alternatively, the rings are the set of curves described by double the arc length of $\sqrt{r^2-x^2}$. We can use the formula for arc-length to calculate this as $2\int_{-r}^r\sqrt{1+\left(\frac{\mathrm{d}}{\mathrm{d}x}\sqrt{r^2-x^2}\right)^2}\ \mathrm{d}x=2\int_{-r}^r\frac{r}{\sqrt{r^2-x^2}}\ \mathrm{d}x=2r\int_{-1}^1\frac{1}{\sqrt{1-x^2}}\ \mathrm{d}x=2\pi r$.
The ring has inner radius $r$ and outer radius $R$ with $R>r$. Thus, the edge of the quadrilateral corresponding with the inner edge of the ring will be shorter than the edge of the quadrilateral corresponding with the outer edge of the ring, which is why the quadrilateral is a trapezoid.
For your second question, $\pi$ is defined to be the ratio of a circle's circumference $C$ to its diameter $d$, so, by defintion of $\pi$, $C = \pi d = 2\pi r$