Best online mathematics videos?
77 instructional videos on category theory:
http://www.youtube.com/TheCatsters
I know you said "only one video per post", but I'm not posting 77 times...
I have compiled a list (1500+) of math videos at http://pinterest.com/mathematicsprof/ . If anyone is aware of others, please send them to me.
Most of the talks at MSRI are videotaped and placed on the web here:
http://www.msri.org/communications/vmath/index_html