C#: override a property of the parent class

What you have done there is member hiding. If the class you are deriving from has marked the property as virtual, or is overriding it from it's base (if it has one) you use the override keyword:

public override DateTime NotAfter

The member hiding can be used when the base class has marked it virtual, however if someone cast a reference of your class into the base class and accessed the member, they would bypass your new hiding. With true inheritance using override, this problem does not occur.

As has been noted by someone, this property is not marked virtual:

http://msdn.microsoft.com/en-us/library/system.security.cryptography.x509certificates.x509certificate2.notafter.aspx

Member hiding will allow you to get around this if people use your class directly, but the moment someone casts your class back to a base type, they get the base value:

class MyClass : Cert...

MyClass c = new MyClass();
DateTime foo = c.NotAfter; // Your newly specified property.

Cert cBase = (Cert)c;
foo = cBase.NotAfter; // Oops, base value.  Inheritance cures this, but only with virtual members.