Cannot deserialize the current JSON array (e.g. [1,2,3])

I think the problem you're having is that your JSON is a list of objects when it comes in and it doesnt directly relate to your root class.

var content would look something like this (i assume):

[
  {
    "id": 3636,
    "is_default": true,
    "name": "Unit",
    "quantity": 1,
    "stock": "100000.00",
    "unit_cost": "0"
  },
  {
    "id": 4592,
    "is_default": false,
    "name": "Bundle",
    "quantity": 5,
    "stock": "100000.00",
    "unit_cost": "0"
  }
]

Note: make use of http://jsonviewer.stack.hu/ to format your JSON.

So if you try the following it should work:

  public static List<RootObject> GetItems(string user, string key, Int32 tid, Int32 pid)
    {
        // Customize URL according to geo location parameters
        var url = string.Format(uniqueItemUrl, user, key, tid, pid);

        // Syncronious Consumption
        var syncClient = new WebClient();

        var content = syncClient.DownloadString(url);

        return JsonConvert.DeserializeObject<List<RootObject>>(content);

    }

You will need to then iterate if you don't wish to return a list of RootObject.

---

I went ahead and tested this in a Console app, worked fine.

That's because the json you're getting is an array of your RootObject class, rather than a single instance, change your DeserialiseObject<RootObject> to be something like DeserialiseObject<RootObject[]> (un-tested).

You'll then have to either change your method to return a collection of RootObject or do some further processing on the deserialised object to return a single instance.

If you look at a formatted version of the response you provided:

[
   {
      "id":3636,
      "is_default":true,
      "name":"Unit",
      "quantity":1,
      "stock":"100000.00",
      "unit_cost":"0"
   },
   {
      "id":4592,
      "is_default":false,
      "name":"Bundle",
      "quantity":5,
      "stock":"100000.00",
      "unit_cost":"0"
   }
]

You can see two instances in there.

You can use this to solve your problem:

private async void btn_Go_Click(object sender, RoutedEventArgs e)
{
    HttpClient webClient = new HttpClient();
    Uri uri = new Uri("http://www.school-link.net/webservice/get_student/?id=" + txtVCode.Text);
    HttpResponseMessage response = await webClient.GetAsync(uri);
    var jsonString = await response.Content.ReadAsStringAsync();
    var _Data = JsonConvert.DeserializeObject <List<Student>>(jsonString);
    foreach (Student Student in _Data)
    {
        tb1.Text = Student.student_name;
    }
}