Classification of quasi-split unitary groups
There is a text by Scharlau about "Hermitian...". Also the older book by O'Meara.
The point is that, first, over non-archimedean local fields a quadratic form in five or more variables has an isotropic vector. In case the residue characteristic is not two, this has a reasonably elementary direct proof. Then note that a hermitian form is a (special type of) quadratic form in twice as many variables. Thus, there is no anisotropic hermitian form in more than two variables.
Edit: in response to questioner's comment, "quasi-split" means (reductive and) a "Borel subgroup" defined over the field. Then "Borel subgroup" means parabolic subgroup that remains minimal under extending scalars. If the whole space were decomposable as hyperbolic planes and an anisotropic two-dimensional space, any quadratic extension would produce a "smaller" parabolic (the Borel, here, because the minimal parabolic is still next-to-Borel).
About algebraic groups, J. Tits' article in Corvallis is good, also the book Platonov and Rapinchuk, "Algebraic groups and number theory". Both these pay attention to such rationality properties, while many classics (such as Borel's "Linear algebra groups") emphasize the algebraically closed groundfield case.
As pointed out in comments, there is a detailed survey by Tits from the algebraic group viewpoint in his AMS proceedings paper, along with quite a few references to earlier literature. From the viewpoint of groups over local fields, it's worth looking closely at his table of "indices" at the end of the paper. There he shows concisely which labelled Dyhkin diagrams can occur over various kinds of fields. In particular, you are interested in the twisted type $^2 \! A_n$ with $n$ even. He indicates that in the local field case this diagram can occur only relative to a quadratic extension and corresponds then to a quasi-split special unitary group. In his set-up, "quasi-split" corresponds to the case where $n$ is twice the relative rank $r$ and the Dynkin diagram is folded accordingly. (In general, various special unitary groups over division algebras are possible.)
While Tits does not spell out all the details of how such groups are constructed, he does provide a nice overview of the basic algebraic group theory leading to such a classification list. (Some improvements are contained in his 1971 paper Représentations linéaires irréductibles d'un groupe réductif sur un corps quelconque (MR).) Also, student of his at Bonn named Martin Selbach elaborated further on the theory:
Klassifikationstheorie halbeinfacher algebraischer Gruppen. Diplomarbeit, Univ. Bonn, Bonn, 1973. Bonner Mathematische Schriften, Nr. 83. Mathematisches Institut der Universitat Bonn, Bonn, 1976. v+140 pp.
P.S. For the characteristic 0 theory, presented in a different style, you might try the lecture notes by I. Satake (which I haven't looked at in a long time): Classification theory of semi-simple algebraic groups. With an appendix by M. Sugiura. Notes prepared by Doris Schattschneider. Lecture Notes in Pure and Applied Mathematics, 3. Marcel Dekker, Inc., New York, 1971. viii+149. Satake also used labelled Dynkin diagrams, but with different conventions than Tits ("Satake-Tits diagrams").