convert ascii character to signed 8-bit integer python

Subtract 256 if over 127:

unsigned = ord(character)
signed = unsigned - 256 if unsigned > 127 else unsigned

Alternatively, repack the byte with the struct module:

from struct import pack, unpack
signed = unpack('B', pack('b', unsigned))[0]

or directly from the character:

signed = unpack('B', character)[0]