Difference between Fermi and Riemann normal coordinates
Take a future-directed timelike curve $\gamma= \gamma(\tau)$, $\tau$ being the proper time along $\gamma$ in the spacetime $M$. Assume that $p = \gamma(0)$ is the initial point of $\gamma$.
Fermi coordinates adapted to $\gamma$ are constructed this way.
Consider an orthonormal basis of $T_pM$ with $e_0$ parallel to $\dot{\gamma}$.
Transport the basis $\{e_a\}_{a=0,1,2,3}$ along $\gamma= \gamma(\tau)$ making use of Fermi-Walker's transport. The basis $\{e_a(\tau)\}_{a=0,1,2,3}$ at each point $\gamma(\tau)$ is still orthonormal with $e_0(\tau)$ parallel to $\dot{\gamma}(\tau)$ and is non-rotated (in a precise sense related to the decomposition of Lorentz transformations into pure transformations and rotations) with respect to the initial basis, this is the physical meaning of Fermi-Walker's transport.
Finally construct a coordinate system in a open tube $T$, a neighbourhood of $\gamma$, emitting all spacelike geodesics through $\gamma(\tau)$ with initial tangent vector $\sum_{i=1}^3 v^i e_i(\tau)$, for every $\tau$.
A point $q\in T$ has coordinates $\tau(q), v^1(q), v^2(q), v^3(q)$ where $\sum_{i=1}^3 v^i(q) e_i(\tau(q))$ is the only vector whose associated geodesic reaches $q$ for the value of its parameter $s=1$ and $\tau(q)$ is the only time along $\gamma$ for that this geodesic reaching $q$ exists.
If $\gamma$ itself is a geodesic, then Fermi-Walker's transport becomes the standard parallel transport and Fermi's coordinates become standard Riemannian coordinates adapted to $\gamma$. In this case, using these coordinates in a neighbourhood $T$ of $\gamma$, we have $\Gamma_{ab}^c =0$ exactly on $\gamma$. This property is not valid for Fermi's coordinates however when $\gamma$ is not a geodesic.
A modern reference on the subject is http://arxiv.org/abs/gr-qc/9402010 where also rotating coordinates are discussed.