Difference between Null set and empty set

In measure theory, a null set refers to a set of measure zero. For example, in the reals, $\mathbb R$ with its standard measure (Lebesgue measure), the set of rationals $\mathbb Q$ has measure $0$, so $\mathbb Q$ is a null set in $\mathbb R$. Actually, all finite and countably infinite subsets of $\mathbb R$ have measure $0$. In contrast, the empty set always refers to the unique set with no elements, denoted $\left\{ \right\}$, $\varnothing$ or $\emptyset$.

They aren't the same although they were used interchangeable way back when.

In mathematics, a null set is a set that is negligible in some sense. For different applications, the meaning of "negligible" varies. In measure theory, any set of measure 0 is called a null set (or simply a measure-zero set). More generally, whenever an ideal is taken as understood, then a null set is any element of that ideal.

Whereas an empty set is defined as:

In mathematics, and more specifically set theory, the empty set is the unique set having no elements; its size or cardinality (count of elements in a set) is zero. Some axiomatic set theories ensure that the empty set exists by including an axiom of empty set; in other theories, its existence can be deduced. Many possible properties of sets are trivially true for the empty set.