Disk Usage Analyzer on Synology
Solution 1:
Synology has an App on it's DSM store called Storage Analyzer, which provides a very friendly user interface to view usage by folder, user, file types, duplicates, etc... It also keeps a history by analyzing periodically...
Solution 2:
NCDU is the closest I can find. Works really well though. Simple to use as you only have to copy the file to the diskstation, then terminal in and run. Some more instructions:
http://forum.synology.com/enu/viewtopic.php?f=90&t=82232
Solution 3:
Mount the Synology volume from a Linux workstation running Gnome, and run Disk Usage Analyzer on it.