Eigenvalues of matrix sums
The problem of describing the possible eigenvalues of the sum of two hermitian matrices in terms of the spectra of the summands leads into deep waters. The most complete description was conjectured by Horn, and has now been proved by work of Knutson and Tao (and others?) - for a good discussion, see the Notices AMS article by those two authors
Depending on what you want, there should be simpler results giving estimates on the eigenvalues of the sum. A book like Bhatia's Matrix Analysis might have some helpful material.
A simple estimate which is often useful is that, if $A$ and $B$ are Hermitian matrices with eigenvalues $a_1 > a_2 > \ldots > a_n$ and $b_1 > b_2 > \ldots > b_n$ and the eigenvalues of the sum are $c_1 > c_2 > \ldots > c_n$, then $$ c_{i+j-1} \le a_i + b_j \quad\text{and}\quad c_{n-i-j} \ge a_{n-i} + b_{n-j}. $$ The above conditions are necessary but not sufficient for $A+B=C$ to have a solution; see the Knutson-Tao article if you want sufficient conditions.
If you do not impose that $A$ and $B$ are Hermitian then there are very few restrictions besides the trace being equal. More specifically, the $3n$-tuples $(a_1, \ldots, a_n, b_1, \ldots, b_n, c_1, \ldots, c_n)$ which occur as eigenvalues of $(A,B,C)$ with $A+B=C$ are dense in the hyperplane $\sum a_i + \sum b_i = \sum c_i$.
If 2 positive matrices commute, than each eigenvalue of the sum is a sum of eigenvalues of the summands. This would be true more generally for commuting normal matrices. For arbitrary positive matrices, the largest eigenvalue of the sum will be less than or equal to the sum of the largest eigenvalues of the summands.