Enabling WiFi-Direct on Mac
Mac's don't have Wifi Direct capabilities in current version os OSX. Hence any device that uses WiFi direct (Android phones, Samsung cameras), instead of supporting AdHoc networking, will not work.
This might help.
Part of the article says:
Since we don’t have WiFi Direct capability on a Macbook, we can emulate it using other means. We will make the Mac as a WiFi Direct Server while the Android Smartphone will be a client. Once the connectivity has been established, we can transfer the files via ES File explorer using Windows File Sharing.