fill na in one column in oython code example

Example: DataFrame.fillna

>>> df.fillna(0)
    A   B   C   D
0   0.0 2.0 0.0 0
1   3.0 4.0 0.0 1
2   0.0 0.0 0.0 5
3   0.0 3.0 0.0 4