Finding $\lim\limits_{n\to\infty}\frac1{n^2}\int_0^{\frac{\pi}2}x\left(\frac{\sin nx}{\sin x}\right)^4\,\mathrm dx$
From $$\lim_{x\to 0}x^2\left(\frac1{\sin^4 x}-\frac1{x^4}\right)=\frac23,$$ for $x\in(0,\frac\pi 2)$, there is $C$ such that $$\left|\frac{x\sin^4 nx}{\sin^4 x}-\frac{\sin^4 nx}{x^3}\right|\le \frac{C\sin^4 nx}{x}\le Cn.$$
Thus, \begin{align*} \lim_{n\to\infty}\frac1{n^2}\int_0^{\frac\pi2}x\left(\frac{\sin nx}{\sin x}\right)^4\, \mathrm dx&=\lim_{n\to\infty}\frac1{n^2}\int_0^{\frac\pi2}\frac{\sin^4 nx}{x^3}\, \mathrm dx\\ &= \lim_{n\to\infty}\int_0^{\frac{n\pi}2}\frac{\sin^4 x}{x^3}\, \mathrm dx\\ &= \int_0^{\infty}\frac{\sin^4 x}{x^3}\, \mathrm dx\\ \text{(IBP)}\quad &= \int_0^{\infty}\frac{2\sin^3 x\cos x}{x^2}\, \mathrm dx\\ \text{(IBP)}\quad &= \int_0^{\infty}\frac{6\sin^2 x\cos^2 x-2\sin^4 x}{x}\, \mathrm dx\\ &= \int_0^{\infty}\frac{\cos 2x-\cos 4x}{x}\, \mathrm dx\\ \text{(Frullani)}\quad &=\ln 2. \end{align*}
Result
Let
$$f(n) = \int_0^{\frac{\pi }{2}} x \left(\frac{\sin (n x)}{\sin (x)}\right)^4 \, dx$$
then
$$\lim_{n\to \infty } \, \frac{f(n)}{n^2}=\log (2)\simeq 0.6931471805599453 ...$$
This result is in good agreement with the numerical estimate of the integral.
Derivation
This is more heuristic and not really strict. Maybe others can fill in the gaps.
We split the integral into equally spaced intervals, and observe $\sin(\pi x/n) \simeq \pi x/n$ for $n\to \infty$ and get
$$\lim_{n\to \infty }f(n)/n^2 =\lim_{n\to \infty } \sum_{k=1}^\infty a(k)\tag{1}$$
where
$$a(k) = \int_{k-1}^k \pi ^2 s \left(\frac{\sin (\pi s)}{\pi s}\right)^4 \, ds$$
The first two values are
$$a(1) = \text{Ci}(2 \pi )-\text{Ci}(4 \pi )+\log (2)$$ $$a(2) = -\text{Ci}(-8 \pi )+\text{Ci}(-4 \pi )-\text{Ci}(2 \pi )+\text{Ci}(4 \pi )$$
and for $k \ge 3$
$$a(k) = -\text{Ci}(2 (k-1) \pi )+\text{Ci}(4 (k-1) \pi )-\text{Ci}(-4 k \pi )+\text{Ci}(-2 k \pi )$$
Here $\text{Ci}(z) = -\int_{-\infty }^z \frac{\cos (t)}{t} \, dt$ is the cosine integral.
The sum in $(1)$ telescopes and we are left with the announced result.
Discussion
My statement "the sum telescopes" is fairly bold.
In fact, the cancellation is like this
$$\text{Ci}(-4 \pi )-\text{Ci}(4 \pi )=i \pi$$ $$\text{Ci}(8 \pi )-\text{Ci}(-8 \pi )=-i \pi$$
see symmetry relations in http://people.math.sfu.ca/~cbm/aands/abramowitz_and_stegun.pdf, 5.2.20, and the sum of these two lines is $0$.