How do I sort a VARCHAR column in SQL server that contains numbers?

There are a few possible ways to do this.

One would be

SELECT
 ...
ORDER BY
  CASE 
    WHEN ISNUMERIC(value) = 1 THEN CONVERT(INT, value) 
    ELSE 9999999 -- or something huge
  END,
  value

the first part of the ORDER BY converts everything to an int (with a huge value for non-numerics, to sort last) then the last part takes care of alphabetics.

Note that the performance of this query is probably at least moderately ghastly on large amounts of data.

One possible solution is to pad the numeric values with a character in front so that all are of the same string length.

Here is an example using that approach:

select MyColumn
from MyTable
order by 
    case IsNumeric(MyColumn) 
        when 1 then Replicate('0', 100 - Len(MyColumn)) + MyColumn
        else MyColumn
    end

The 100 should be replaced with the actual length of that column.