How do you upload a file to a document library in sharepoint?

if you get this error "Value does not fall within the expected range" in this line:

SPFolder myLibrary = oWeb.Folders[documentLibraryName];

use instead this to fix the error:

SPFolder myLibrary = oWeb.GetList(URL OR NAME).RootFolder;

Use always URl to get Lists or others because they are unique, names are not the best way ;)

You can upload documents to SharePoint libraries using the Object Model or SharePoint Webservices.

Upload using Object Model:

String fileToUpload = @"C:\YourFile.txt";
String sharePointSite = "http://yoursite.com/sites/Research/";
String documentLibraryName = "Shared Documents";

using (SPSite oSite = new SPSite(sharePointSite))
{
    using (SPWeb oWeb = oSite.OpenWeb())
    {
        if (!System.IO.File.Exists(fileToUpload))
            throw new FileNotFoundException("File not found.", fileToUpload);                    

        SPFolder myLibrary = oWeb.Folders[documentLibraryName];

        // Prepare to upload
        Boolean replaceExistingFiles = true;
        String fileName = System.IO.Path.GetFileName(fileToUpload);
        FileStream fileStream = File.OpenRead(fileToUpload);

        // Upload document
        SPFile spfile = myLibrary.Files.Add(fileName, fileStream, replaceExistingFiles);

        // Commit 
        myLibrary.Update();
    }
}