How to do group by on a multiindex in pandas?

You can create the index on the existing dataframe. With the subset of data provided, this works for me:

import pandas
df = pandas.DataFrame.from_dict(
    {
     'category': {0: 'Love', 1: 'Love', 2: 'Fashion', 3: 'Fashion', 4: 'Hair', 5: 'Movies', 6: 'Movies', 7: 'Health', 8: 'Health', 9: 'Celebs', 10: 'Celebs', 11: 'Travel', 12: 'Weightloss', 13: 'Diet', 14: 'Bags'}, 
     'impressions': {0: 380, 1: 374242, 2: 197, 3: 13363, 4: 4, 5: 189, 6: 60632, 7: 269, 8: 40189, 9: 138, 10: 66590, 11: 2227, 12: 22668, 13: 21707, 14: 229}, 
     'date': {0: '2013-11-04', 1: '2013-11-04', 2: '2013-11-04', 3: '2013-11-04', 4: '2013-11-04', 5: '2013-11-04', 6: '2013-11-04', 7: '2013-11-04', 8: '2013-11-04', 9: '2013-11-04', 10: '2013-11-04', 11: '2013-11-04', 12: '2013-11-04', 13: '2013-11-04', 14: '2013-11-04'}, 'cpc_cpm_revenue': {0: 0.36823, 1: 474.81522000000001, 2: 0.19434000000000001, 3: 18.264220000000002, 4: 0.00080000000000000004, 5: 0.23613000000000001, 6: 81.391139999999993, 7: 0.27171000000000001, 8: 51.258200000000002, 9: 0.11536, 10: 83.966859999999997, 11: 3.43248, 12: 31.695889999999999, 13: 28.459320000000002, 14: 0.43524000000000002}, 'clicks': {0: 0, 1: 183, 2: 0, 3: 9, 4: 0, 5: 1, 6: 20, 7: 0, 8: 21, 9: 0, 10: 32, 11: 1, 12: 12, 13: 9, 14: 2}, 'size': {0: '300x250', 1: '300x250', 2: '300x250', 3: '300x250', 4: '300x250', 5: '300x250', 6: '300x250', 7: '300x250', 8: '300x250', 9: '300x250', 10: '300x250', 11: '300x250', 12: '300x250', 13: '300x250', 14: '300x250'}
    }
)
df.set_index(['date', 'category'], inplace=True)
df.groupby(level=[0,1]).sum()

If you're having duplicate index issues with the full dataset, you'll need to clean up the data a bit. Remove the duplicate rows if that's amenable. If the duplicate rows are valid, then what sets them apart from each other? If you can add that to the dataframe and include it in the index, that's ideal. If not, just create a dummy column that defaults to 1, but can be 2 or 3 or ... N in the case of N duplicates -- and then include that field in the index as well.

Alternatively, I'm pretty sure you can skip the index creation and directly groupby with columns:

df.groupby(by=['date', 'category']).sum()

Again, that works on the subset of data that you posted.