Apple - How to enable push notifications of emails?
You're talking about the notification settings for Mail, not whether push is on. To see new mail messages in the Lock Screen:
Settings > Notifications > Mail > Make sure "View in Lock Screen" is turned ON.
If you're concerned about your mail's push settings, those are in:
Settings > Mail, Contacts, Calendar > Fetch New Data > Make sure "Push" is set how you want it.