How to Export Private / Secret ASC Key to Decrypt GPG Files

All the above replies are correct, but might be missing one crucial step, you need to edit the imported key and "ultimately trust" that key

gpg --edit-key (keyIDNumber)
gpg> trust

Please decide how far you trust this user to correctly verify other users' keys
(by looking at passports, checking fingerprints from different sources, etc.)

  1 = I don't know or won't say
  2 = I do NOT trust
  3 = I trust marginally
  4 = I trust fully
  5 = I trust ultimately
  m = back to the main menu

and select 5 to enable that imported private key as one of your keys

You can export the private key with the command-line tool from GPG. It works on the Windows-shell. Use the following command:

gpg --export-secret-keys

A normal export with --export will not include any private keys, therefore you have to use --export-secret-keys.

Edit:

To sum up the information given in my comments, this is the command that allows you to export a specific key with the ID 1234ABCD to the file secret.asc:

gpg --export-secret-keys --armor 1234ABCD > secret.asc

You can find the ID that you need using the following command. The ID is the second part of the second column:

gpg --list-keys

To Export just 1 specific secret key instead of all of them:

gpg --export-secret-keys keyIDNumber > exportedKeyFilename.asc

keyIDNumber is the number of the key id for the desired key you are trying to export.