how to find the first letter of a word in python code example

Example 1: print first word of a string python and return it

def print_first_word():
    words = "All good things come to those who wait"
    print(words.split().pop(0))
    #to print the last word use pop(-1)
print_first_word()

Example 2: how to find the first letter of an item in python

mylist[0][0]   # get the first character from the first item in the list