How to find the limit of $\frac{\sqrt{x^2+9}-3}{x^2}$? as x approaches 0
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Multiplying by the conjugate is the right thing to do! Let's multiply the fraction by $\sqrt{x^2+9}+3$. Therefore
$$\lim\limits_{x\to0}\frac {\sqrt{x^2+9}-3}{x^2}=\lim\limits_{x\to0}\frac {(\sqrt{x^2+9}-3)(\sqrt{x^2+9}+3)}{x^2(\sqrt{x^2+9}+3)}=\lim\limits_{x\to0}\frac {x^2+9-9}{x^2(\sqrt{x^2+9}+3)}$$
The numerator reduces down to $x^2$, and we see that both $x^2$ terms cancel each other out. Can you finish the rest?
$$\lim\limits_{x\to0}\frac {1}{\sqrt{x^2+9}+3}=\frac 1{\sqrt9+3}=\frac 16$$
Edit: The OP has provided his work on the problem. The denominator is actually supposed to be $3x^2$ and not $-3x^2$ because we're multiplying by the conjugate: $\sqrt{x^2+9}+3$.
With $f (x)=\sqrt {x+9} $, the limit is
$$\lim_0\frac {f (x)-f (0)}{x}=f'(0) $$
and $$f'(x)=\frac {1}{2f (x)} $$
thus $$f'(0)=1/6$$
Note: \begin{align*} \frac{\sqrt{x^2+9}-3}{x^2} = & \; \frac{\big(\sqrt{x^2+9}-3 \big) \big(\sqrt{x^2+9}+3 \big)}{x^2 \big( \sqrt{x^2+9}+3 \big)} \\ = & \; \frac{x^2+9-3^2}{x^2\big(\sqrt{x^2+9}+3 \big)} \\ = & \; \frac{1}{\sqrt{x^2+9} + 3}. \end{align*} So we have \begin{align*} \lim_{x \to 0} \frac{\sqrt{x^2+9}-3}{x^2} = \lim_{x \to 0} \frac{1}{\sqrt{x^2+9} + 3} = \frac{1}{\sqrt{9}+3}=\frac{1}{6}. \end{align*} I guess you made some mistake when you multiplied the conjugate.