How to query values from xml nodes?

This works, been tested...

SELECT  n.c.value('OrganizationReportReferenceIdentifier[1]','varchar(128)') AS 'OrganizationReportReferenceNumber',  
        n.c.value('(OrganizationNumber)[1]','varchar(128)') AS 'OrganizationNumber'
FROM    Batches t
Cross   Apply RawXML.nodes('/GrobXmlFile/Grob/ReportHeader') n(c)  

SELECT  b.BatchID,
        x.XmlCol.value('(ReportHeader/OrganizationReportReferenceIdentifier)[1]','VARCHAR(100)') AS OrganizationReportReferenceIdentifier,
        x.XmlCol.value('(ReportHeader/OrganizationNumber)[1]','VARCHAR(100)') AS OrganizationNumber
FROM    Batches b
CROSS APPLY b.RawXml.nodes('/CasinoDisbursementReportXmlFile/CasinoDisbursementReport') x(XmlCol);

Demo: SQLFiddle

Try this:

SELECT RawXML.value('(/GrobXmlFile//Grob//ReportHeader//OrganizationReportReferenceIdentifier/node())[1]','varchar(50)') AS ReportIdentifierNumber,
       RawXML.value('(/GrobXmlFile//Grob//ReportHeader//OrganizationNumber/node())[1]','int') AS OrginazationNumber
FROM Batches