How to redirect links in email template to salesforce1 app
You can place links in email templates that navigate to the Salesforce1 app in the following format:
com.salesforce.salesforce1://entity/view?entityId={Account.Id}
I suggest you put that in alongside the standard {Account.Link}
and give users a choice.
e.g.
To view this record please select either:
{Account.Link}
to view this in your browser
com.salesforce.salesforce1://entity/view?entityId={Account.Id}
to open in Salesforce1*