How to sum a variable by group

You can also use the dplyr package for that purpose:

library(dplyr)
x %>% 
  group_by(Category) %>% 
  summarise(Frequency = sum(Frequency))

#Source: local data frame [3 x 2]
#
#  Category Frequency
#1    First        30
#2   Second         5
#3    Third        34

Or, for multiple summary columns (works with one column too):

x %>% 
  group_by(Category) %>% 
  summarise(across(everything(), sum))

Here are some more examples of how to summarise data by group using dplyr functions using the built-in dataset mtcars:

# several summary columns with arbitrary names
mtcars %>% 
  group_by(cyl, gear) %>%                            # multiple group columns
  summarise(max_hp = max(hp), mean_mpg = mean(mpg))  # multiple summary columns

# summarise all columns except grouping columns using "sum" 
mtcars %>% 
  group_by(cyl) %>% 
  summarise(across(everything(), sum))

# summarise all columns except grouping columns using "sum" and "mean"
mtcars %>% 
  group_by(cyl) %>% 
  summarise(across(everything(), list(mean = mean, sum = sum)))

# multiple grouping columns
mtcars %>% 
  group_by(cyl, gear) %>% 
  summarise(across(everything(), list(mean = mean, sum = sum)))

# summarise specific variables, not all
mtcars %>% 
  group_by(cyl, gear) %>% 
  summarise(across(c(qsec, mpg, wt), list(mean = mean, sum = sum)))

# summarise specific variables (numeric columns except grouping columns)
mtcars %>% 
  group_by(gear) %>% 
  summarise(across(where(is.numeric), list(mean = mean, sum = sum)))

For more information, including the %>% operator, see the introduction to dplyr.

Using aggregate:

aggregate(x$Frequency, by=list(Category=x$Category), FUN=sum)
  Category  x
1    First 30
2   Second  5
3    Third 34

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In the example above, multiple dimensions can be specified in the list. Multiple aggregated metrics of the same data type can be incorporated via cbind:

aggregate(cbind(x$Frequency, x$Metric2, x$Metric3) ...

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(embedding @thelatemail comment), aggregate has a formula interface too

aggregate(Frequency ~ Category, x, sum)

Or if you want to aggregate multiple columns, you could use the . notation (works for one column too)

aggregate(. ~ Category, x, sum)

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or tapply:

tapply(x$Frequency, x$Category, FUN=sum)
 First Second  Third 
    30      5     34 

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Using this data:

x <- data.frame(Category=factor(c("First", "First", "First", "Second",
                                      "Third", "Third", "Second")), 
                    Frequency=c(10,15,5,2,14,20,3))