How to use an ALIAS in a PostgreSQL ORDER BY clause?

One solution is to use the position:

select  title, 
        ( stock_one + stock_two ) as global_stock
from product
order by 2, 1

However, the alias should work, but not necessarily the expression. What do you mean by "global_stock = 0"? Do you mean the following:

select  title, 
        ( stock_one + stock_two ) as global_stock
from product
order by (case when global_stock = 0 then 1 else 0 end) desc, title

You can always ORDER BY this way:

select 
    title, 
    ( stock_one + stock_two ) as global_stock
from product
order by 2, 1

or wrap it in another SELECT:

SELECT *
from
(
    select 
        title, 
        ( stock_one + stock_two ) as global_stock
    from product
) x
order by (case when global_stock = 0 then 1 else 0 end) desc, title