14.04 Upgrade triggers grub-pc failure
I "elegantly solved" my problem by using the following:
sudo apt-get purge grub-pc grub-common
sudo rm -r /etc/grub.d/
sudo apt-get install grub-pc grub-common
sudo grub-install /dev/sda
sudo update-grub
Deleting the /etc/grub.d/
directory seemed to have gotten rid of whatever 12.04
files I had lurking, allowing 14.04
to get on with installing grub!
Although I would of course recommend making a backup of anything that you are about to delete.