Adding column between two other columns in SQL server

The simple answer is no. Is there a reason why column order is important to you?

Mediumly long answer, yes (ish) but it's ugly and you probably wouldn't want to do it.

please note: this code creates a physical table

CREATE TABLE MyTest (a int, b int, d int, e int)

INSERT INTO MyTest (a,b,d,e) VALUES(1,2,4,5)

SELECT * FROM MyTest

ALTER TABLE MyTest ADD c int
ALTER TABLE MyTest ADD d_new int
ALTER TABLE MyTest ADD e_new int

UPDATE MyTest SET d_new = d, e_new = e

ALTER TABLE MyTest DROP COLUMN d
ALTER TABLE MyTest DROP COLUMN e

EXEC SP_RENAME 'MyTest.d_new', 'd';
EXEC SP_RENAME 'MyTest.e_new', 'e';

SELECT * FROM MyTest 

DROP TABLE MyTest

Take a look at this link:

http://www.bobsgear.com/display/ts/Adding+Column+After+Another+Column+-+SQL+Server+2005

As you can see, the answer is:

'not possible without moving data to a temp table'

which is what the SQL Server Management Studio actually does.

Yes you can add here is the query for your concern:

ALTER table table_name ADD column column_name(new) datatype AFTER column_name