Can the torus and the Klein bottle be thought as $\mathbb{R}^2/G$ with $G$ a finite group acting freely
There is some lovely topological machinery you can learn about called covering space theory, and it tells you a lot about quotients like this. Among other things, it tells you that if $X$ is simply connected and $G$ is a finite group acting freely on it, then $X$ is a finite covering space of $X/G$, and $X/G$ has fundamental group $G$.
The torus and the Klein bottle both have infinite fundamental groups. Also, any quotient $\mathbb{R}^2/G$ would be noncompact, and the torus and the Klein bottle are compact. So these are two ways of seeing that neither can occur as a quotient $\mathbb{R}^2/G$ for $G$ finite; they both occur as such a quotient, but for $G$ infinite.
Every finite covering space of the torus is another torus, meaning that if $X$ is any manifold and $G$ a finite group acting freely on it such that $X/G \cong T^2$, then $X$ itself must already be a torus. So it's impossible to use this technique to prove non-circularly that the torus is a manifold. On the other hand, the torus is the orientation double cover of the Klein bottle, meaning there's an action of the cyclic group $C_2$ of order $2$ on the torus whose quotient is the Klein bottle.
Fortunately it is easier than this to prove that the torus and the Klein bottle are manifolds.
What the covering space arguments further reveal is the following perhaps surprising fact: no nontrivial finite group acts freely on $\mathbb{R}^2$, because the only connected surface with nontrivial finite fundamental group is $\mathbb{RP}^2$, whose universal cover is $S^2$, not $\mathbb{R}^2$.
While not being a finite group, $\Bbb{Z}^2$ acts on $\Bbb{R}^2$ by translation (concretely $(n,m) \cdot (a,b) :=(a+n,b+m)$) and the torus arises as the quotient space for this action.
Similarly, let $f,g:\Bbb{R}^2\to \Bbb{R}^2$ be the bijections given by $(a,b)\mapsto (a,b+1)$ and $(a,b)\mapsto (a+1, 1-b)$ respectively. If $G$ denotes the (infinite!) group generated by $f$ and $g$, the quotient $\Bbb{R}^2/G$ is the Klein bottle. You may check this by inspecting how the points in $[0,1]^2$ are identified by the action.
In both cases, the action is properly discontinuous: this ensures that each point in the quotient has a locally euclidean neighborhood (since the quotient map is a local homeomorphism). The fact that $\Bbb{R}^2/G$ is Hausdorff is not automatic, but is implied by the hypothesis
for each $x,y\in\Bbb{R}^2$ with disjoint orbits, there exist neighborhoods $U\ni x$, $V\ni y$ such that $gU\cap V$ is empty for each $g\in G$,
which is easily verified in both examples (and is in fact automatic provided $G$ is finite).