Connection between spatial, temporal, and spacetime curvature?
I think the essential problem lies in the difference between the mathematical meaning of curvature, and the way in which we actually describe a manifold, or a curved space (or spacetime).
Although we describe the universe as having spacetime curvature (which is mathematically true), curvature refers to the Riemann curvature tensor, which is a rank-4 tensor, meaning that it has $4^4 =256$ components, of which (due to various symmetries) $20$ are independent. This is far too cumbersome for even mathematicians to think about, but what is certainly true is that you cannot separate it nicely into space curvature and time curvature. As @G.Smith says in comments, "temporal curvature" does not make any sense. Time is a single dimension, and a one-dimensional subspace does not have any Riemannian curvature.
In other words, we use the mathematics of curved spacetime, but we don't actually describe anything directly in terms of Riemannian curvature. We do write Einstein's equation for gravity using the Einstein curvature tensor (or Ricci) but since this is zero except in the presence of mass-energy (the source of gravity), it does not directly tell us about the geometry of spacetime; to know that we have to solve Einstein's equation.
When we do solve Einstein's equation, we do not find curvature as such. Instead we find the metric. The metric is much easier to think about than curvature (we can write down a formula from which we could calculate curvature given the metric, but actually we never bother with that horrible calculation).
Rather than think about curvature, we think about scaling distortions in maps. In other words, we choose a coordinate system, and think about how actual or proper quantities appear in those coordinates. Proper quantities are the physical properties which would be measured by an observer moving with the object being measured.
We can compare this to scaling distortions in maps of the surface of the Earth. Any number of different maps are possible. The metric for the map tells us how to compare apparent distances on the map to actual distances as measured by someone on the ground.
So, rather than talk of curvature, talk of scaling distortions in maps. Then your question makes sense. For example, we cannot directly measure scaling distortions in Euclidean geometry in the region of the Earth, because they are too small. But we can, and do, measure scaling distortions in time. Clocks on GPS satellites measure the same unit of time as identical clocks on Earth. They measure exactly one second per second (as required by the general principle of relativity). But they appear on Earth to run at a different rate, because of the scaling distortion in the map used to describe them. Indeed, we can explain Newtonian gravity completely in terms of the scaling distortion of the time component, the scaling distortions of the space components being too small to have any impact.
The spacetime metric of a spatially-flat Friedmann universe — like ours seems to be, on the largest scales — is
$$ds^2=-dt^2+a(t)^2(dx^2+dy^2+dz^2)$$
where the function $a(t)$ is the Friedmann scale factor describing the expansion of space as a function of cosmological time $t$.
You can calculate its 4D Riemann curvature tensor $R_{\mu\nu\lambda\kappa}$ and find that it has various nonzero components involving the first and second time derivatives of $a(t)$. (Even some components where all four indices are spatial are nonzero!) This is an example of spacetime curvature.
Now take a spacelike slice through this spacetime at some constant cosmological time $t_0$.
The metric of this 3D space is
$$ds^2=a(t_0)^2(dx^2+dy^2+dz^2)$$
where the prefactor $a(t_0)^2$ is just some constant that could be absorbed into the coordinates to rescale them.
You can calculate its 3D Riemann curvature tensor and find that every component is zero. (This should be obvious, because it’s just a Euclidean metric.) This is an example of spatial flatness, or zero spatial curvature.
Temporal curvature doesn’t exist because there is only one time dimension and one-dimensional (sub)spaces always have zero Riemannian curvature.
The notion of "spatial curvature" only makes sense when the spacetime geometry is symmetric enough that there is a natural/preferred foliation of it into spacelike slices. You can then talk about the intrinsic curvature of those slices.
The easiest way to understand why the curvatures can be different is to look at a toy cosmological model, like the "expanding balloon" picture: 3D Euclidean space, with time being distance to the origin. The locus of space"time" points with a given time coordinate in this model is a 2D space of constant positive curvature, but the 3D background space"time" has zero curvature.
A slightly more realistic toy model is the analogous one in 3+1D Minkowski space: the interior of the future light cone of the origin, with time being the (timelike) distance to the origin. The locus of points with a given time coordinate is a 3D space of constant negative curvature. This model is in fact the zero-energy-density or zero-$G$ limit of any expanding FLRW cosmology. As you add energy density, or add gravity, the spacetime becomes positively curved. The spatial slices get an increasing curvature, which reaches zero at the critical density, and is positive at higher densities. The FLRW time coordinate is analogous to the radial coordinate of a polar coordinate system on a curved surface, like the surface of the earth, which is of course where the name "polar" came from. The time coordinate is the latitude, and the position coordinates are the longitude.