Destructuring-bind dictionary contents
One way to do this with less repetition than Jochen's suggestion is with a helper function. This gives the flexibility to list your variable names in any order and only destructure a subset of what is in the dict:
pluck = lambda dict, *args: (dict[arg] for arg in args)
things = {'blah': 'bleh', 'foo': 'bar'}
foo, blah = pluck(things, 'foo', 'blah')
Also, instead of joaquin's OrderedDict you could sort the keys and get the values. The only catches are you need to specify your variable names in alphabetical order and destructure everything in the dict:
sorted_vals = lambda dict: (t[1] for t in sorted(dict.items()))
things = {'foo': 'bar', 'blah': 'bleh'}
blah, foo = sorted_vals(things)
from operator import itemgetter
params = {'a': 1, 'b': 2}
a, b = itemgetter('a', 'b')(params)
Instead of elaborate lambda functions or dictionary comprehension, may as well use a built in library.