Difference between Return and Break statements

break is used to exit (escape) the for-loop, while-loop, switch-statement that you are currently executing.

return will exit the entire method you are currently executing (and possibly return a value to the caller, optional).

So to answer your question (as others have noted in comments and answers) you cannot use either break nor return to escape an if-else-statement per se. They are used to escape other scopes.

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Consider the following example. The value of x inside the while-loop will determine if the code below the loop will be executed or not:

void f()
{
   int x = -1;
   while(true)
   {
     if(x == 0)
        break;         // escape while() and jump to execute code after the the loop 
     else if(x == 1)
        return;        // will end the function f() immediately,
                       // no further code inside this method will be executed.

     do stuff and eventually set variable x to either 0 or 1
     ...
   }

   code that will be executed on break (but not with return).
   ....
}

break is used when you want to exit from the loop, while return is used to go back to the step where it was called or to stop further execution.