Expected number of unique items when drawing with replacement
Let $Y$ be the number of unique items that get picked. Let $X_i$ be $1$ if item $i$ gets picked and $0$ if not. We have $E[X_i] = 1 P(X_i = 1) + 0 P(X_i = 0) = P(X_i = 1) = 1 - P(X_i = 0)$. Since $P(X_i = 0)$ is the probability that item $i$ is not picked, this is the probability that $i$ is not picked with any of the first, second, third, etc., choices. Thus $P(X_i = 0) = \left(\frac{M-1}{M}\right)^M$.
Therefore, $$\begin{align}E[Y] &= E\left[\sum_{i=1}^M X_i\right] = \sum_{i=1}^M E[X_i] = \sum_{i=1}^M P(X_i = 1) = \sum_{i=1}^M \left(1 - \left(\frac{M-1}{M}\right)^M\right) \\ &= M - \frac{(M-1)^M}{M^{M-1}}.\end{align}$$
In general, using indicator functions to calculated expected values can be very helpful. For more examples, see the answers to Find the expectation or Another balls and bins question or Expected number of neighbors.
Thanks for great answer Mike!
I just would like to add that if someone is interested in percent of picked items, then $$ \frac{M - \frac{(M-1)^M}{M^{M-1}}}{M} = \frac{M - M\left(\frac{M-1}{M} \right)^M}{M} = 1 - \left(1 - \frac{1}{M} \right )^M $$
For large M it is approximately $$ 1 - \frac{1}{e} \simeq 0.632120559 \dots $$
because
$$ \lim_{M\to\infty}\left(1 - \frac{1}{M} \right )^M = \frac{1}{e} $$