Get all mysql selected rows into an array

I would suggest the use of MySQLi or MySQL PDO for performance and security purposes, but to answer the question:

while($row = mysql_fetch_assoc($result)){
     $json[] = $row;
}

echo json_encode($json);

If you switched to MySQLi you could do:

$query = "SELECT * FROM table";
$result = mysqli_query($db, $query);

$json = mysqli_fetch_all ($result, MYSQLI_ASSOC);
echo json_encode($json );

1. Loop through the results and place each one in an array

2. use mysqli_fetch_all() to get them all at one time