Get enum values from web.config at run time

You can use ConfigurationManager and convert value to enum:

<configuration> 
  <appSettings>
    <add key="YourEnum" value="BlueSky" />  
  </appSettings>
</configuration>

string configValue = ConfigurationManager.AppSettings["YourEnum"];
YourEnumType value = (YourEnumType)Enum.Parse(typeof(YourEnumType), configValue);