Growth rate of the nth natural number not constructable with n steps of addition and multiplication
Let's suppose that $\psi(n)=k+1$. It thus follows that
$$\{x:x\in[0,k]\}\subset C(n)$$
By adding these together, we may find that
$$\{k+x:x\in C(n)\}\subset C(n+1)$$
And thus, the simple bound of
$$\psi(n+1)\ge k+k+1=2\psi(n)-1$$
or
$$\psi(n)\ge2^n+1$$
By adding and multiplying, we find that
$$\{k+x,k\cdot x:x\in C(n)\}\subset C(n+1)$$
And by adding these again, we find that
$$\{k\cdot x_0+x_1:x_0,x_1\in C(n)\}\subset C(n+2)$$
Which encompasses all of the numbers from $0$ to $k^2+2k$, hence
$$\psi(n+2)\ge k^2+2k+1=\psi(n)^2$$
or,
$$\psi(n)\ge2^{2^{n/2}}$$
By adding and multiplying instead of just adding in the previous step, we find that
$$\{x_0,x_1k^2:x_0,x_1\in C(n+1)\}\subset C(n+2)$$
And by adding these, once again, we find that
$$\{x_1k^2+x_0:x_0,x_1\in C(n+1)\}\subset C(n+3)$$
which will encompass all of the numbers from $0$ to $2k^3+2k$, hence
$$\psi(n+3)\ge2k^3+2k+1=2\psi(n)^3-6\psi(n)^2+8\psi(n)-3$$
which is not at all pretty, but since $2\psi(n)\ge1$ for all $n$, we get
$$\psi(n+3)\ge2(\psi(n)-1)^3$$
And if $\psi(n)\ge\frac1{1-2^{-1/3}}\approx4.8$, then
$$2(\psi(n)-1)^3\ge\psi(n)^3$$
And thus,
$$\psi(n)\ge5^{3^{(n-2)/3}},{\rm~large~enough~}n$$
Doing this again gives
$$\psi(n+4)\ge2k^5+4k^4+2k^3+k^2+2k$$
And for large enough $k$,
$$2k^5+4k^4+2k^3+k^2+2k>(k+1)^5=\psi(n)^5$$
hence,
$$\psi(n)\ge5^{5^{(n-2)/4}},{\rm~large~enough~}n$$
and in general, I'm expecting
$$\psi(n)\ge2^{(2^x+1)^{(n-y)/(x+2)}}>2^{2^{x(n-y)/(x+2)}}$$
For all $x$, large enough $n$, and some $y$.