How are $SU(n)$, $SL(n)$ and $\mathfrak{sl}(n,\mathbb{C})$ related?
Very short answer: You have to be very precise about which base field, $\mathbb R$ or $\mathbb C$, you are considering in each case.
Over $\mathbb C$, there is the Lie group $SL_n(\mathbb C)$ and its Lie algebra $\mathfrak{sl}_n(\mathbb C)$, and every Cartan subalgebra of this will have roots which form a system of type $A_{n-1}$. There is extensive literature on this.
Over $\mathbb R$ however, one can e.g. look at the Lie groups $SL_n(\mathbb R)$, which have Lie algebra $\mathfrak{sl}_n(\mathbb R)$, but also at the Lie groups $SU(n)$ and their Lie algebras $\mathfrak{su}_n$ -- note that elements of these are often written as certain matrices with complex entries, but they are not complex Lie groups resp. algebras, but real ones. Notice in particular that $\mathfrak{su}_n$, which indeed can be identified with the traceless skew-hermitian $n\times n$-matrices, is not a vector space over $\mathbb C$, but over $\mathbb R$ (of dimension $n^2-1$).
Now it turns out that the non-isomorphic real Lie groups $SL_n(\mathbb R)$ and $SU_n$ both have complexification (isomorphic to) $SL_n(\mathbb C)$. They are so-called real forms of $SL_n(\mathbb C)$. Likewise but even simpler to see -- on the Lie algebra level, complexification is just done by tensoring with $\mathbb C$ -- both $\mathbb C \otimes_{\mathbb R}\mathfrak{su}_n$ and $\mathbb C \otimes_{\mathbb R}\mathfrak{sl}_n(\mathbb R)$ are isomorphic to $\mathfrak{sl}_n(\mathbb C)$, i.e. both $\mathfrak{su}_n$ and $\mathfrak{sl}_n(\mathbb R)$ are real forms of $\mathfrak{sl}_n(\mathbb C)$.
For $n=2$, $SL_2(\mathbb R)$ and $SU_2$ are (up to isomorphism) the only real forms of $SL_2(\mathbb C)$. For higher $n$ though, and for other classes of Lie groups / algebras, there are usually more real forms. The last example here is a real form of $\mathfrak{sl}_3(\mathbb C)$, called $\mathfrak{su}_{1,2}$, which is neither isomorphic to $\mathfrak{sl}_3(\mathbb R)$ nor to $\mathfrak{su}_3$.
It's quite common in the literature when speaking of root systems, what is meant is actually the root system of the complexification. In that terminology, both $SL_n(\mathbb R)$ and $SU_n$ (or their Lie algebras) have root system $A_{n-1}$. However, there is also the notion of relative or restricted or real or $k$-rational (here for $k=\mathbb R$) root systems; in this case, the relative root system of $SL_n(\mathbb R)$ would still be $A_{n-1}$, whereas the relative root system of $SU_n$ is empty (which is always the case for compact semisimple groups). More on those "relative roots" e.g. here, where I tried to compute all examples of real forms where that restricted root system is of type $BC$ (something that can never happen for complex Lie groups / algebras).
One further thing to note: By a fantastic coincidence (?), for each complex simple Lie algebra, there is up to iso exactly one real form which is compact (e.g. above, $\mathfrak{su}_n$ is the compact real form of $\mathfrak{sl}_n(\mathbb C)$). Also, there is always exactly one so-called "split" real form, whose restricted roots are just the same as the roots of the complexified version (e.g. above $\mathfrak{sl}_n(\mathbb R)$ is the split real form of $\mathfrak{sl}_n(\mathbb C)$). In a way, these two are extreme cases on opposite ends of a spectrum. As noted above, in general there are many more cases "between" them. They are classified by so-called "Satake diagrams", which are like an upgrade of the Dynkin diagrams: the underlying Dynkin diagram of a Satake diagram tells us of what type ($A_n, B_n, C_n, ..., G_2$) the complexification is, and the extra ornaments that make it a Satake diagram (black vs. white nodes, and arrows) encode which real form of that complex type we have. See further references and examples here or here.
Added: It's maybe worthwhile to note that beyond everything mentioned above, the (Lie group / Lie algebra)-correspondence is also not one-to-one, over any ground field. Rather, for one given semisimple Lie algebra there is a lattice of connected groups that "sits" over it, with an adjoint (centreless) one at the bottom and a simply connected one on top. E.g. over $\mathbb C$,
$PSL_2(\mathbb C)$ (adjoint) and $SL_2(\mathbb C)$ (simply connected) share the Lie algebra $\mathfrak{sl}_2(\mathbb C)$;
whereas over $\mathbb R$,
$PSL_2(\mathbb R)$ (adjoint), $SL_2(\mathbb R)$, $Mp_2(\mathbb R)$ (the metaplectic group), ... , $\overline {SL_2(\mathbb R)}$ (the simply connected universal cover of $SL_2(\mathbb R)$), with the "..." being infinitely more in-between, all share the Lie algebra $\mathfrak{sl}_2(\mathbb R)$ (compare last three sentences here);
whereas the compact real one has only two manifestations again:
$PSU_2$ (adjoint, and happens to be $\simeq SO_3(\mathbb R)$) and $SU_2$ (simply connected) share the Lie algebra $\mathfrak{su}_2$.
If one allows even disconnected groups, then there's infinitely many more groups sitting over each Lie algebra, but that's basically stuff like
$SL_2(\mathbb C) \times$ (your favourite finite group) still has Lie algebra $\mathfrak{sl}_2(\mathbb C)$.