How can I check percent GPU usage on Windows?

If you use an older Windows version that doesn't show the GPU usage in Taskmanager you can use ProcessExplorer to show the GPU usage:

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in system information of in a column (View --> Select Columns --> Process GPU --> GPU Usage):

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An opensource solution is Process Hacker which also offers GPU usage in system information (via CTRL+I)

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and as column (right click on header and click "Choose columns"):

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What method or tool could I use to detect actual GPU percent usage?

You can use Task Manager in Windows 10 Version 1709+

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Find out how hard your GPU is working with Windows Task Manager