How can I find an element by CSS class with XPath?

This selector should work but will be more efficient if you replace it with your suited markup:

//*[contains(@class, 'Test')]

Or, since we know the sought element is a div:

//div[contains(@class, 'Test')]

But since this will also match cases like class="Testvalue" or class="newTest", @Tomalak's version provided in the comments is better:

//div[contains(concat(' ', @class, ' '), ' Test ')]

If you wished to be really certain that it will match correctly, you could also use the normalize-space function to clean up stray whitespace characters around the class name (as mentioned by @Terry):

//div[contains(concat(' ', normalize-space(@class), ' '), ' Test ')]

Note that in all these versions, the * should best be replaced by whatever element name you actually wish to match, unless you wish to search each and every element in the document for the given condition.

Most easy way..

//div[@class="Test"]

Assuming you want to find <div class="Test"> as described.