How to change the plot line color from blue to black?

The usual way to set the line color in matplotlib is to specify it in the plot command. This can either be done by a string after the data, e.g. "r-" for a red line, or by explicitely stating the color argument.

import matplotlib.pyplot as plt

plt.plot([1,2,3], [2,3,1], "r-") # red line
plt.plot([1,2,3], [5,5,3], color="blue") # blue line

plt.show()

See also the plot command's documentation.

In case you already have a line with a certain color, you can change that with the lines2D.set_color() method.

line, = plt.plot([1,2,3], [4,5,3], color="blue")
line.set_color("black")

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Setting the color of a line in a pandas plot is also best done at the point of creating the plot:

import matplotlib.pyplot as plt
import pandas as pd

df = pd.DataFrame({ "x" : [1,2,3,5], "y" : [3,5,2,6]})
df.plot("x", "y", color="r") #plot red line

plt.show()

If you want to change this color later on, you can do so by

plt.gca().get_lines()[0].set_color("black")

This will get you the first (possibly the only) line of the current active axes.
In case you have more axes in the plot, you could loop through them

for ax in plt.gcf().axes:
    ax.get_lines()[0].set_color("black")

and if you have more lines you can loop over them as well.

If you have more than one plot line and you want to set a different color for each line, use the attribute below in your plot() where each index represents a line color for a column.

color=['color1','color2']