How to check the first character in a string in Bash or UNIX shell?

Many ways to do this. You could use wildcards in double brackets:

str="/some/directory/file"
if [[ $str == /* ]]; then echo 1; else echo 0; fi

You can use substring expansion:

if [[ ${str:0:1} == "/" ]] ; then echo 1; else echo 0; fi

Or a regex:

if [[ $str =~ ^/ ]]; then echo 1; else echo 0; fi

Consider the case statement as well which is compatible with most sh-based shells:

case $str in
/*)
    echo 1
    ;;
*)
    echo 0
    ;;
esac

$ foo="/some/directory/file"
$ [ ${foo:0:1} == "/" ] && echo 1 || echo 0
1
$ foo="[email protected]:/some/directory/file"
$ [ ${foo:0:1} == "/" ] && echo 1 || echo 0
0