How to check what user php is running as?

If available you can probe the current user account with posix_geteuid and then get the user name with posix_getpwuid.

$username = posix_getpwuid(posix_geteuid())['name'];

If you are running in safe mode however (which is often the case when exec is disabled), then it's unlikely that your PHP process is running under anything but the default www-data or apache account.

<?php echo exec('whoami'); ?>