how to display toolbox on the left side of window of Visual Studio Express for windows phone 7 development?

Ctrl-Alt-X is the keyboard shortcut I use, although that may because I have Resharper installed - otherwise Ctrl W, X.

From the menu: View -> Toolbox.

You can easily view/change key bindings using Tools -> Options Environment->Keyboard. It has a convenient UI where you can enter a word, and it shows you what key bindings include that word, including View.Toolbox.

You might want to browse through the online MSDN documentation on getting started with Visual Studio.

Just select from the Visual Studio menu View- > ToolBox .

In Visual Studio Express 2013 for web it's hidden away in View > Other Windows > Toolbox.