Linear algebra proofs in combinatorics?

Some other examples are the Erdos-Moser conjecture (see R. Proctor, Solution of two difficult problems with linear algebra, Amer. Math. Monthly 89 (1992), 721-734), a few results at http://math.mit.edu/~rstan/312/linalg.pdf, and Lovasz's famous result on the Shannon capacity of a 5-cycle and other graphs (IEEE Trans. Inform. Theory 25 (1979), 1-7). For a preliminary manuscript of Babai and Frankl on this subject (Linear Algebra Methods in Combinatorics), see http://people.cs.uchicago.edu/~laci/CLASS/HANDOUTS-COMB/BaFrNew.pdf .

The AMS has a new book out, Jiri Matousek, Thirty-three Miniatures: Mathematical and Algorithmic Applications of Linear Algebra. Info at http://www.ams.org/bookstore-getitem/item=STML-53

"This volume contains a collection of clever mathematical applications of linear algebra, mainly in combinatorics, geometry, and algorithms."

Hoffman and Singleton proved that a regular graph with girth 5 and diameter 2 has to have degree 2, 3, 7, or 57. If I recall correctly, the proof used spectral properties of the adjacency matrix to produce some non-polynomial equation for which these were the integer solutions.

There are unique examples of the first three cases: degree 2 is a pentagon, degree 3 is the Petersen graph, and degree 7 is the Hoffman-Singleton graph. The existence of the degree 57 graph is still open (as far as I know).