Mathematical Programming Languages
R / S+ for statistical computing
Other stat languages: SAS, SPSS, STATA, GAUSS, etc.
Octave, an open source clone of Matlab
Fortress, "a language for high-performance computation that provides abstraction and type safety on par with modern programming language principles."
Maple
Maxima
R, Numpy/scipy for Python, Maple, Yacas, even Fortran.
There's always APL, with its builtin matrix operators. Modern APL even supports .NET.