Minimal addition-chain exponentiation
This looks like section 4.6.3 "Evaluation of Powers" in Knuth Vol 2 Seminumerical Algorithms. This goes into considerable detail to give various approaches, which look much quicker than branch and bound but do not all provide the absolutely best solution.
Knuth states in the discussion after Theorem F that he uses backtrack search to prove that l(191) = 11, so I doubt if you will find a short-cut answer for this. He defers explanation of the backtrack search to section 7.2.2, which is I think still unpublished, although there are traces of work on this at http://www-cs-faculty.stanford.edu/~uno/programs.html.