Minimum transactions to settle debts among friends
Unfortunately, in this unbalanced world is hard to achieve equality even among friends. Namely, for this problem exists no polynomial algorithm unless $\mathcal{ P=NP}$, see below.
Put $[n]= \{1,\dots, n\}.$
Propositon. The goal can be achieved in less then $n-1$ moves iff there is a proper subset $S$ of $[n]$ such that $\sum_{i\in S} x_i=0$.
Proof. ($\Leftarrow$) If there exists such a set $S$ then we can annulate all $x_i$ with $i\in S$ by $|S|-1$ moves, and all $x_i$ with $i\in [n]\setminus S$ by $|[n]\setminus S |-1$ moves. Thus we can achieve the goal in at most $|S|-1+|[n]\setminus S |-1=n-2$ moves in total.
($\Rightarrow$) Assume that the friends can annulate all $x_i$ using $k<n-1$ moves. Consider a graph $G$ with the set $[n]$ of vertices such that the vertices $i$ and $j$ are adjacent by an edge of weight $a$ iff there was a pay of $a$ between $i$-th and $j$-th friend. Since the graph $G$ has less than $n-1$ edges, it has at least two connected components. Clearly, $\sum_{i\in S} x_i=0$ for each component $S$. $\square$
At last we remark that it is NP-hard to decide whether there exists a proper subset $S$ of $[n]$ such that $\sum_{i\in S} x_i=0$, because this problem is equivalent to Subset sum problem, which is NP-hard. Indeed, given integers $x_1,\dots, x_{n-1}$ and $x_n=-\sum_{i\in [n-1]} x_i$, there exists a subset $S$ of $[n-1]$ such that $\sum_{i\in S} x_i=0$ iff there exists a proper subset $S’$ of $[n]$ such that $\sum_{i\in S’} x_i=0$.
Suppose we have some minimum size set of payments, then I claim the resulting (undirected!) payment graph is always a forest. Indeed, suppose the graph has a cycle, then we can adjust all the payments on this cycle by $\pm 1$ until one of the edges becomes a payment of $0$ and disappears. We can use this procedure to find an optimal way to resolve any $S \subseteq [n]$ with $\sum_{i\in S} x_i = 0$ using $|S|-1$ payments.
Clearly then, an optimal solution will partition $[n]$ into subsets $S_1,\dots,S_k$ such that $\sum_{i\in S_j} x_i = 0$ for all $1\leq j \leq k$ and resolve each subset using $|S_j|-1$ payments. In other words, the optimal solution has value $n - k$ where $[n] = S_1 \cup \dots \cup S_k$ is the largest decomposition into subsets summing to $0$.
However, note that if $S_1$ and $S_2$ sum to $0$, then so does $S_1 \cup S_2$, so equivalently we may find a maximum length chain $\emptyset \neq S_1 \subseteq \dots \subseteq S_k = [n]$ and resolve all sets $S_{i+1} \setminus S_i$ individually using $|S_{i+1} \setminus S_i|-1$ payments. We can find such a maximum length chain in $O(n2^n)$ time by precomputing for every subset $S \subseteq [n]$ the value $s(S) = \sum_{i\in S} x_i$ and then just using the recurrence:
$$b(S) = \begin{cases} 0 & \text{if $S = \emptyset$} \\ 1 + \max_{u\in S} b(S\setminus\{u\}) & \text{if $s(S) = 0$} \\ 0 + \max_{u\in S} b(S\setminus\{u\}) & \text{if $s(S) \neq 0$} \\ \end{cases} $$
This is again $O(n2^n)$ time. As was pointed out in the other answer we are unlikely to find a polynomial time algorithm.