Preserving column order in the pandas to_csv method

Try the following solution. Even I faced the same issue. I solved it as follows:

import pandas as pd
df = pd.DataFrame({'V_pod_error' : [a],
                   'V_pod_used' : [b],
                   'U_sol_type' : [c]
                                ...
                                ... and so on upto 50 columns }

column_order = ['V_pod_error', 'V_pod_used', 'U_sol_type',.....# upto 50 column names]

df[column_order].to_csv(file_name)

I think problem is in DataFrame constructor, because you need add parameter columns for custom ordering of columns. If you dont set parameter columns, columns are ordered alphanumerical.

import pandas as pd
df = pd.DataFrame({'V_pod_error' : [0,2],
                   'V_pod_used' : [6,4],
                   'U_sol_type' : [7,8]})
print df
   U_sol_type  V_pod_error  V_pod_used
0           7            0           6
1           8            2           4

print df.to_csv()
,U_sol_type,V_pod_error,V_pod_used
0,7,0,6
1,8,2,4


df1 = pd.DataFrame({'V_pod_error' : [0,2],
                   'V_pod_used' : [6,4],
                   'U_sol_type' : [7,8]}, 
                    columns=['V_pod_error','V_pod_used','U_sol_type'])

print df1
   V_pod_error  V_pod_used  U_sol_type
0            0           6           7
1            2           4           8

print df1.to_csv()
,V_pod_error,V_pod_used,U_sol_type
0,0,6,7
1,2,4,8

EDIT:

Another solution is set order of column by subset before write to_csv (thanks Mathias711):

import pandas as pd
df = pd.DataFrame({'V_pod_error' : [0,2],
                   'V_pod_used' : [6,4],
                   'U_sol_type' : [7,8]})
print df
   U_sol_type  V_pod_error  V_pod_used
0           7            0           6
1           8            2           4

df = df[['V_pod_error','V_pod_used','U_sol_type']]
print df

   V_pod_error  V_pod_used  U_sol_type
0            0           6           7
1            2           4           8

EDIT1: Maybe help first convert dict to OrderedDict and then create DataFrame:

import collections
import pandas as pd


d = {'V_pod_error' : [0,2],'V_pod_used' : [6,4], 'U_sol_type' : [7,8]}
print d
{'V_pod_error': [0, 2], 'V_pod_used': [6, 4], 'U_sol_type': [7, 8]}

print pd.DataFrame(d)
   U_sol_type  V_pod_error  V_pod_used
0           7            0           6
1           8            2           4

d1 = collections.OrderedDict(d)
print d1
OrderedDict([('V_pod_error', [0, 2]), ('V_pod_used', [6, 4]), ('U_sol_type', [7, 8])])

print pd.DataFrame(d1)
   V_pod_error  V_pod_used  U_sol_type
0            0           6           7
1            2           4           8