Python: 'break' outside loop

Because break cannot be used to break out of an if - it can only break out of loops. That's the way Python (and most other languages) are specified to behave.

What are you trying to do? Perhaps you should use sys.exit() or return instead?

Because break can only be used inside a loop. It is used to break out of a loop (stop the loop).

break breaks out of a loop, not an if statement, as others have pointed out. The motivation for this isn't too hard to see; think about code like

for item in some_iterable:
    ...
    if break_condition():
        break 

The break would be pretty useless if it terminated the if block rather than terminated the loop -- terminating a loop conditionally is the exact thing break is used for.