Regaining usage of volume control media keys after removing pulseaudio
ArchWiki page provided explanations, and creating the following files worked for me:
/etc/acpi/actions/volume
#! /bin/sh
step=5
case $1 in
-) amixer set Master $step-;;
+) amixer set Master $step+;;
esac
/etc/acpi/events/volume_down
event=button/volumedown
action=/etc/acpi/actions/volume -
/etc/acpi/events/volume_up
event=button/volumeup
action=/etc/acpi/actions/volume +