Apple - Ruby 2.0.0 install via RVM: errors surrounding openssl

Had the same problem. Try the following:

$ rvm remove 2.0.0 # get rid of unsuccessful installation
$ rvm get head --autolibs=3 # get the latest RVM and build required libs
$ rvm requirements # just in case, install all other required stuff
$ rvm install ruby-2.0.0
$ rvm --default use ruby-2.0.0