Storing Data In Memory: Session vs Cache vs Static

I'll vote for secret option #4: use the database for this. If you're talking about a 20+ second turnaround time on the data, you are not going to gain anything by trying to do this in-memory, given the limitations of the options you presented. You might as well set this up in the database (give it a table of its own, or even a separate database if the requirements are that large).